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Hydrogen is the most abundant element in the universe, making up ~75% of all matter.
Did you know?
Hydrogen is the most abundant element in the universe, making up ~75% of all matter.
Nitration of aniline in strong acidic medium also gives m-nitroaniline because
In absence of substituents, nitro group always goes to m-position.
In electrophilic substitution reactions, amino group is meta directive.
In spite of substituents, nitro group always goes to only m-position.
In acidic (strong) medium, aniline is present as anilinium ion.
To solve this problem, we need to understand the behavior of aniline in a strong acidic medium during nitration.Aniline is an aromatic amine with the structure The amino group is a strong activating group and ortho/para directing in electrophilic aromatic substitution reactions.However, in a strong acidic medium, the amino group gets protonated to form the anilinium ion Step-by-step explanation:1. In a strong acidic medium, aniline is protonated:2. The anilinium ion is a deactivated form of aniline.โข The positive charge on the nitrogen reduces the electron density on the benzene ring.โข This makes the ring less reactive towards electrophilic substitution.3. The anilinium ion is meta-directing:โข The positive charge on the nitrogen withdraws electrons from the ortho and para positions.โข This makes the meta position relatively more electron-rich compared to ortho and para positions.4. As a result, nitration in a strong acidic medium leads to the formation of m-nitroaniline.Analyzing the options:โข Option 1: Incorrect, as the nitro group does not always go to the meta position in absence of substituents.โข Option 2: Incorrect, as the amino group is not meta-directing in its neutral form.โข Option 3: Incorrect, as the nitro group does not always go to the meta position despite substituents.โข Option 4: Correct, as in acidic medium, aniline is present as anilinium ion, which is meta-directing.Therefore, the correct option is Option 4.
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